American Elements
Carbonylchlorobis(triphenylphosphine)iridium(I)
IrCl(CO)[P(C6H5)3]2
14871-41-1
Product
Product Code
Order or Specifications
99% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-02
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99.5% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-025
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99.9% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-03
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99.95% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-035
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99.99% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-04
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99.999% Carbonylchlorobis(triphenylphosphine)iridium(I)
IR-OM2-05
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Carbonylchlorobis(triphenylphosphine)iridium(I) is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Carbonylchlorobis(triphenylphosphine)iridium(I) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Iridium is a Block D, Group 9, Period 6 element. The electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs.

Formula CAS No. Appearance Molecular Weight
IrCl(CO)[P(C6H5)3]2 14871-41-1 780.27
CATALOGUE PRODUIT Submicroniques et nanopoudres Tolling Ultra haute pureté Sputtering Public Crystal Growth Rod, Plate, poudre, etc.
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Recent Research & Development for Iridium Metal

  • Is the Treatment of Keloid Scars Still a Challenge in 2006?
    Ann Plast Surg. 2007 Feb;58(2):186-192.

  • Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding.
    J Am Chem Soc. 2007 Jan 31;129(4):853-66.

  • Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes.
    J Am Chem Soc. 2007 Jan 31;129(4):776-7.

  • Iridium(I)-catalyzed regio- and enantioselective decarboxylative allylic amidation of substituted allyl benzyl imidodicarbonates.
    J Am Chem Soc. 2007 Jan 31;129(4):774-5.

  • Design and optimization of molecular nanovalves based on redox-switchable bistable rotaxanes.
    J Am Chem Soc. 2007 Jan 24;129(3):626-34.

  • Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers.
    J Am Chem Soc. 2007 Jan 24;129(3):588-600.

  • High Enantioselectivity Is Induced by a Single Monodentate Phosphoramidite Ligand in Iridium-Catalyzed Asymmetric Hydrogenation.
    Angew Chem Int Ed Engl. 2007 Jan 16; [Epub ahead of print] No abstract available.

  • Hydrogen-Atom Transfer in Open-Shell Organometallic Chemistry: The Reactivity of Rh(II)(cod) and Ir(II)(cod) Radicals.
    Chemistry. 2007 Jan 12; [Epub ahead of print]

  • Iridium-Catalyzed C-C Bond Forming Hydrogenation: Direct Regioselective Reductive Coupling of Alkyl-Substituted Alkynes to Activated Ketones.
    J Am Chem Soc. 2007 Jan 17;129(2):280-281.

  • Unresectable hilar cholangiocarcinoma: multimodality approach with percutaneous treatment associated with radiotherapy and chemotherapy.
    In Vivo. 2006 Nov-Dec;20(6A):757-60.

 

 

 

 

 

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