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Samaria doped Ceria (SDC) Cerium Oxide stabilized with Samarium Oxide |
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CeO2/Sm2O3 |
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American Elements specializes in producing samaria doped ceria (SDC), cerium oxide stabilized by various doping levels of yttrium oxide, a material that upon firing forms a highly ionically conductive thin film electrolyte layer for use in solid oxide fuel cell electrochemistry structures. Samarium Oxide doped Ceria belongs to a class of doped Ceria compounds with ionic conductivity exceeding yttria stabilized zirconia (YSZ) electrolytes. These include yttria doped ceria (YDC) and gadolinium doped ceria (GDC). Even higher conductivity can be achieved with American Elements Scandia doped Zirconia (SCZ) and Yttria doped Bismuth Oxide. Samarium Oxide doped Cerium Oxide is available in a powder for tape casting, air spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Samaria doping levels are available at 10% and 20% and as specified by customer. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' cathode and anode cell layers.
Cerium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f26s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. It is, therefore, strongly acidic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors.
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